Minseok Choi

Two-dimensional (2D) molybdenum disulphide (MoS2) atomic layers have a strong potential to be used as 2D electronic sensor components. However, intrinsic synthesis challenges have made this task difficult. In addition, the detection mechanisms for gas molecules are not fully understood. Here, we report a high-performance gas sensor constructed using atomic-layered MoS2 synthesised by chemical vapour deposition (CVD). A highly sensitive and selective gas sensor based on the CVD-synthesised MoS2 was developed. In situ photoluminescence characterisation revealed the charge transfer mechanism between the gas molecules and MoS2, which was validated by theoretical calculations. First-principles density functional theory calculations indicated that NO2 and NH3 molecules have negative adsorption energies (i.e., the adsorption processes are exothermic). Thus, NO2 and NH3 molecules are likely to adsorb onto the surface of the MoS2. The in situ PL characterisation of the changes in the peaks corresponding to charged trions and neutral excitons via gas adsorption processes was used to elucidate the mechanisms of charge transfer between the MoS2 and the gas molecules.

-type doping, the compensation of carrier electrons by the native acceptor-type defects can be mostly suppressed when O-poor chemical potential conditions, i.e. low O partial pressure conditions, are chosen during crystal growth and/or doping.

The high-volume synthesis of two-dimensional (2D) materials in the form of platelets is desirable for various applications. While water is considered an ideal dispersion medium, due to its abundance and low cost, the hydrophobicity of platelet surfaces has prohibited its widespread use. Here we exfoliate 2D materials directly in pure water without using any chemicals or surfactants. In order to exfoliate and disperse the materials in water, we elevate the temperature of the sonication bath, and introduce energy via the dissipation of sonic waves. Storage stability greater than one month is achieved through the maintenance of high temperatures, and through atomic and molecular level simulations, we further discover that good solubility in water is maintained due to the presence of platelet surface charges as a result of edge functionalization or intrinsic polarity. Finally, we demonstrate inkjet printing on hard and flexible substrates as a potential application of water-dispersed 2D materials.

We performed hybrid functional calculations of native point defects and dangling bonds (DBs) in α-Al2O3 to aid in the identification of charge-trap and fixed-charge centers in Al2O3/III-V metal-oxide-semiconductor structures. We find that Al vacancies (VAl) are deep acceptors with transition levels less than 2.6 eV above the valence band, whereas Al interstitials (Ali) are deep donors with transition levels within ∼2 eV of the conduction band. Oxygen vacancies (VO) introduce donor levels near midgap and an acceptor level at ∼1 eV below the conduction band, while oxygen interstitials (Oi) are deep acceptors, with a transition level near the mid gap. Taking into account the band offset between α-Al2O3 and III-V semiconductors, our results indicate that VO and Al DBs act as charge traps (possibly causing carrier leakage), while VAl, Ali, Oi, and O DBs act as fixed-charge centers in α-Al2O3/III-V metal-oxide-semiconductor structures.