Tandem Photoredox and Copper-Catalyzed Decarboxylative C(sp<sup>3</sup>)–N Coupling of Anilines and Imines Using an Organic Photocatalyst
Guido Barzanò(École Polytechnique Fédérale de Lausanne), Runze Mao(École Polytechnique Fédérale de Lausanne), Marion Garreau(École Polytechnique Fédérale de Lausanne), Jérôme Waser(École Polytechnique Fédérale de Lausanne), Xile Hu(École Polytechnique Fédérale de Lausanne)
Cited by 55Open Access
Abstract
An organic photoredox catalyst, 4CzIPN, was used in combination with a copper catalyst, CuCl, to effect decarboxylative C(sp3)–N coupling. The coupling worked with both anilines and imines as nitrogen sources and could be used to prepare a variety of alkyl amines from readily available alkyl carboxylic acids.
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