Separation of Xylene Isomers through Multiple Metal Site Interactions in Metal–Organic Frameworks

Miguel I. Gonzalez(University of California, Berkeley), Matthew T. Kapelewski(University of California, Berkeley), Eric D. Bloch(University of California, Berkeley), Phillip J. Milner(University of California, Berkeley), Douglas A. Reed(University of California, Berkeley), Matthew R. Hudson(National Institute of Standards and Technology), Jarad A. Mason(University of California, Berkeley), Gökhan Barın(University of California, Berkeley), Craig M. Brown(National Institute of Standards and Technology), Jeffrey R. Long(Lawrence Berkeley National Laboratory)
Journal of the American Chemical Society
February 15, 2018
10.1021/jacs.7b13825
Cited by 218Open Access
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Abstract

(dobdc) exhibits an unexpected structural distortion in the presence of either o-xylene or ethylbenzene that enables the accommodation of additional guest molecules.

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