Jeffrey R. Long

ADVERTISEMENT RETURN TO ISSUEEditorialNEXTIntroduction to Metal–Organic FrameworksHong-Cai Zhou, Jeffrey R. Long, and Omar M. YaghiView Author Information Texas A&M University University of California, Berkeley University of California, BerkeleyCite this: Chem. Rev. 2012, 112, 2, 673–674Publication Date (Web):January 26, 2012Publication History Published online26 January 2012Published inissue 8 February 2012https://pubs.acs.org/doi/10.1021/cr300014xhttps://doi.org/10.1021/cr300014xeditorialACS PublicationsCopyright © 2012 American Chemical Society. This publication is available under these Terms of Use. Request reuse permissions This publication is free to access through this site. Learn MoreArticle Views212040Altmetric-Citations5979LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail PDF (2 MB) Get e-AlertscloseSUBJECTS:Adsorption,Chemical structure,Crystal structure,Hydrogen,Metal organic frameworks Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTCarbon Dioxide Capture in Metal–Organic FrameworksKenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, and Jeffrey R. Long*View Author Information Department of Chemistry, University of California, Berkeley, California 94720-1460, United States*E-mail: [email protected]Cite this: Chem. Rev. 2012, 112, 2, 724–781Publication Date (Web):December 28, 2011Publication History Received19 August 2011Published online28 December 2011Published inissue 8 February 2012https://pubs.acs.org/doi/10.1021/cr2003272https://doi.org/10.1021/cr2003272review-articleACS PublicationsCopyright © 2011 American Chemical SocietyRequest reuse permissionsArticle Views81380Altmetric-Citations5582LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Adsorption,Materials,Membranes,Metal organic frameworks,Selectivity Get e-Alerts

New materials capable of storing hydrogen at high gravimetric and volumetric densities are required if hydrogen is to be widely employed as a clean alternative to hydrocarbon fuels in cars and other mobile applications. With exceptionally high surface areas and chemically-tunable structures, microporous metal-organic frameworks have recently emerged as some of the most promising candidate materials. In this critical review we provide an overview of the current status of hydrogen storage within such compounds. Particular emphasis is given to the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H(2) interactions, and strategies for improving storage capacity (188 references).

The escalating level of atmospheric carbon dioxide is one of the most pressing environmental concerns of our age. Carbon capture and storage (CCS) from large point sources such as power plants is one option for reducing anthropogenic CO(2) emissions; however, currently the capture alone will increase the energy requirements of a plant by 25-40%. This Review highlights the challenges for capture technologies which have the greatest likelihood of reducing CO(2) emissions to the atmosphere, namely postcombustion (predominantly CO(2)/N(2) separation), precombustion (CO(2)/H(2)) capture, and natural gas sweetening (CO(2)/CH(4)). The key factor which underlies significant advancements lies in improved materials that perform the separations. In this regard, the most recent developments and emerging concepts in CO(2) separations by solvent absorption, chemical and physical adsorption, and membranes, amongst others, will be discussed, with particular attention on progress in the burgeoning field of metal-organic frameworks.

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