Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application

Arava Leela Mohana Reddy(Rice University), Anchal Srivastava(Rice University), Sanketh R. Gowda(Rice University), Hemtej Gullapalli(Rice University), Madan Dubey(DEVCOM Army Research Laboratory), Pulickel M. Ajayan(Rice University)
ACS Nano
October 8, 2010
Cited by 1,642

Abstract

We demonstrate a controlled growth of nitrogen-doped graphene layers by liquid precursor based chemical vapor deposition (CVD) technique. Nitrogen-doped graphene was grown directly on Cu current collectors and studied for its reversible Li-ion intercalation properties. Reversible discharge capacity of N-doped graphene is almost double compared to pristine graphene due to the large number of surface defects induced due to N-doping. All the graphene films were characterized by Raman spectroscopy, transmission electron microscopy, and X-ray photoemission spectroscopy. Direct growth of active electrode material on current collector substrates makes this a feasible and efficient process for integration into current battery manufacture technology.


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