Swiatoslaw Trofimenko

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRecent advances in poly(pyrazolyl)borate (scorpionate) chemistryS. TrofimenkoCite this: Chem. Rev. 1993, 93, 3, 943–980Publication Date (Print):May 1, 1993Publication History Published online1 May 2002Published inissue 1 May 1993https://pubs.acs.org/doi/10.1021/cr00019a006https://doi.org/10.1021/cr00019a006research-articleACS PublicationsRequest reuse permissionsArticle Views6943Altmetric-Citations1361LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCoordination chemistry of pyrazole-derived ligandsSwiatoslaw. TrofimenkoCite this: Chem. Rev. 1972, 72, 5, 497–509Publication Date (Print):October 1, 1972Publication History Published online1 May 2002Published inissue 1 October 1972https://pubs.acs.org/doi/10.1021/cr60279a003https://doi.org/10.1021/cr60279a003research-articleACS PublicationsRequest reuse permissionsArticle Views4345Altmetric-Citations618LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

This work deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, which have become increasingly popular with inorganic, organometallic and co-ordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically though appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in co-ordination chemistry (first stable CuCO complex, first monomeric MgR complex). Over 170 different scorpoinate ligands are known today. This book is intended as a reference work, placing at the researcher's command almost all of the 1500 or more references on the subject up to 1999, organized both according to the ligand type and according to the metal or metalloid being co-ordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances.