Huanxi Zheng

Conventional understanding has it that a liquid deposited on a surface tends to move along directions that reduce surface energy, which is mainly dictated by surface properties rather than liquid properties, such as surface tension. Achieving well-controlled directional steering remains challenging because the liquid-solid interaction mainly occurs in the two-dimensional (2D) domain. We show that the spreading direction of liquids with different surface tensions can be tailored by designing 3D capillary ratchets that create an asymmetric and 3D spreading profile both in and out of the surface plane. Such directional steering is also accompanied by self-propulsion and high flow velocity, all of which are preferred in liquid transport.

poor adhesion), as well as limited sensation performances. Here, we report a dopamine-triggered gelation (DTG) strategy for fabricating mussel-inspired, transparent, and conductive hydrogels. The DTG design leverages on the dual functions of dopamine, which serves as both polymerization initiator and dynamic mediator to elaborate and orchestrate the cross-linking networks of hydrogels, allowing for pronounced adhesion, robust elasticity, self-healing ability, excellent injectability and three-dimensional printability, reversible and tunable transparent-opaque transition, and thermoresponsive feature. These preferable performances enable DTG hydrogels as self-adhesive, flexible skinlike sensors for achieving multiple sensations toward pressure, strain, and temperature, even an extraordinary visual perception effect, making it a step closer in the exploration of future biomimetic skin.

Despite their simplicity, water droplets manifest a wide spectrum of forms and dynamics, which can be actuated using special texture at solid surfaces to achieve desired functions. Along this vein, natural or synthetic materials can be rendered water repellent, oleophobic, antifogging, anisotropic, etc.-all properties arising from an original design of the substrate and/or from the use of special materials promoting capillary or elastic forces at the droplet scale. Here, we report an original phenomenon occurring at the tip of asymmetric (half-flat, half-curved) pillars: Droplets reconfigure and get oriented on the curved side of these Janus tips. This local, geometry-driven effect, namely, tip-induced flipping of droplets, is found to be generic and have spectacular global consequences: Vast assemblies of Janus pillars enable a continuous, long-range, and fast self-transport of water harvested from fogs, which makes it possible to collect and concentrate droplets at different scales.

Energy harvesting devices that prosper in harsh environments are highly demanded in a wide range of applications ranging from wearable and biomedical devices to self-powered and intelligent systems. Particularly, over the past several years, the innovation of triboelectric nanogenerators (TENGs) that efficiently convert ambient kinetic energy of water droplets or wave power to electricity has received growing attention. One of the main bottlenecks for the practical implications of such devices originates from the fast degradation of the physiochemical properties of interfacial materials under harsh environments. To overcome these challenges, here we report the design of a novel slippery lubricant-impregnated porous surface (SLIPS) based TENG, referred to as SLIPS-TENG, which exhibits many distinctive advantages over conventional design including optical transparency, configurability, self-cleaning, flexibility, and power generation stability, in a wide range of working environments. Unexpectedly, the slippery and configurable lubricant layer not only serves as a unique substrate for liquid/droplet transport and optical transmission, but also for efficient charge transfer. Moreover, we show that there exists a critical thickness in the liquid layer, below which the triboelectric effect is almost identical to that without the presence of such a liquid film. Such an intriguing charge transparency behavior is reminiscent of the wetting transparency and van der Waals potential transparency of graphene previously reported, though the fundamental mechanism remains to be elucidated. We envision that the marriage of these two seemingly totally different arenas (SLIPS and TENG) provides a paradigm shift in the design of robust and versatile energy devices that can be used as a clean and longer-lifetime alternative in various working environments.