Li Yang

Abstract Photocatalytic hydrogen production has been considered a promising approach to obtain green hydrogen energy. Crystalline porous materials have arisen as key photocatalysts for efficient hydrogen production. Here, we report a strategy to in situ photodeposit platinum clusters as cocatalyst on a covalent organic framework, which makes it an efficient photocatalyst for light-driven hydrogen evolution. Periodically dispersed adsorption sites of platinum species are constructed by introducing adjacent hydroxyl group and imine-N in the region of the covalent organic framework structural unit where photogenerated electrons converge, leading to the in situ reduction of the adsorbed platinum species into metal clusters by photogenerated electrons. The widespread platinum clusters on the covalent organic framework expose large active surface and greatly facilitate the electron transfer, finally contributing to a high photocatalytic hydrogen evolution rate of 42432 μmol g −1 h −1 at 1 wt% platinum loading. This work provides a direction for structural design on covalent organic frameworks to precisely manipulate cocatalyst morphologies and positions at the atomic level for developing efficient photocatalysts.

The rechargeable Li–O 2 battery has attracted much attention over the past decades owing to its overwhelming advantage in theoretical specific energy density compared to state‐of‐the‐art Li‐ion batteries. Practical application requires non‐aqueous Li–O 2 batteries to stably obtain high reversible capacity, which highly depends on a suitable electrolyte system. Up to now, some critical challenges remain in developing desirable non‐aqueous electrolytes for Li–O 2 batteries. Herein, we will review the current status and challenges in non‐aqueous liquid electrolytes, ionic liquid electrolytes and solid‐state electrolytes of Li–O 2 batteries, as well as the perspectives on these issues and future development.

Due to fragmentized terrain and physiognomy of typical loess landform, long-term anthropogenic influences, and inherent vulnerability, soil erosion is a serious problem in the Loess Plateau of China. There is a critical need to assess soil erosion and spatial distribution for achieving sustainable land use and comprehensive soil conservation management. Taking the Yangou watershed as a case and using the Landsat Thematic Mapper image (land use map), Digital Elevation Model (DEM), soil maps, and precipitation data, this study integrated the revised universal soil loss equation (RUSLE) with GIS technology to estimate soil loss and its spatial distribution. The benefits of soil conservation of land use types were analyzed and the measures for future soil conservation planning were discussed. The results show that silt-covered land and terrace have high benefits of soil conservation, indicating that building check dam, producing silt-covered land for farming, and converting sloped farmland to terrace are effective ways to control soil erosion in the Yangou watershed. Furthermore, increasing vegetation coverage on lower coverage grassland, especially on the slopes with gradients >25°, and eliminating human disturbance in barren areas are feasible and effective measures for soil conservation planning. This study reveals that the integrated RUSLE-GIS model can evaluate and map soil erosion quantitatively and spatially at watershed scale in the Loess Plateau of China. The findings suggest strategies for coping with future soil conservation planning and provide valuable references for future assessments both in the Loess Plateau of China and elsewhere.