Jaehyeok Park

Abstract Making small nanograins in polycrystalline organic–inorganic halide perovskite (OIHP) films is critical to improving the luminescent efficiency in perovskite light‐emitting diodes (PeLEDs). 3D polycrystalline OIHPs have fundamental limitations related to exciton binding energy and exciton diffusion length. At the same time, passivating the defects at the grain boundaries is also critical when the grain size becomes smaller. Molecular additives can be incorporated to shield the nanograins to suppress defects at grain boundaries; however, unevenly distributed molecular additives can cause imbalanced charge distribution and inefficient local defect passivation in polycrystalline OIHP films. Here, a kinetically controlled polycrystalline organic‐shielded nanograin (OSN) film with a uniformly distributed organic semiconducting additive (2,2′,2′′‐(1,3,5‐benzinetriyl)‐tris(1‐phenyl‐1‐ H ‐benzimidazole), TPBI) is developed mimicking core–shell nanoparticles. The OSN film causes improved photophysical and electroluminescent properties with improved light out‐coupling by possessing a low refractive index. Finally, highly improved electroluminescent efficiencies of 21.81% ph el −1 and 87.35 cd A −1 are achieved with a half‐sphere lens and four‐time increased half‐lifetime in polycrystalline PeLEDs. This strategy to make homogeneous, defect‐healed polycrystalline core–shell‐mimicked nanograin film with better optical out‐coupling will provide a simple and efficient way to make highly efficient perovskite polycrystal films and their optoelectronics devices.

Abstract Although light flickering at 40 Hz reduced Alzheimer’s disease (AD) pathologies in mice by entraining gamma waves, it failed to reduce cerebral amyloid burden in a study on six patients with AD or mild cognitive impairment. We investigated the optimal color, intensity, and frequency of the flickering light stimulus for entraining gamma waves in young adults. We compared the event-related synchronization (ERS) values of entrained gamma waves between four different light colors (white, red, green, and blue) in the first experiment and four different luminance intensities in the second experiment. In both experiments, we compared the ERS values of entrained gamma waves between 10 different flickering frequencies from 32 to 50 Hz. We also examined the severity of six adverse effects in both experiments. We compared the propagation of gamma waves in the visual cortex to other brain regions between different luminance intensities and flickering frequencies. We found that red light entrained gamma waves most effectively, followed by white light. Lights of higher luminance intensities (700 and 400 cd/m 2 ) entrained stronger gamma waves than those of lower luminance intensities (100 and 10 cd/m 2 ). Lights flickering at 34–38 Hz entrained stronger and more widely spread beyond the visual cortex than those flickering at 40–50 Hz. Light of 700 cd/m 2 resulted in more moderate-to-severe adverse effects than those of other luminance intensities. In humans, 400 cd/m 2 white light flickering at 34–38 Hz was most optimal for gamma entrainment.

Abstract Organic light‐emitting diodes (OLEDs) have successfully established themselves as light sources vital in high‐end mobile displays and television due to various advances made for a wide range of technical aspects from materials, devices, and processes to air‐tight packaging and systems. However, a significant portion of the generated excitons in OLEDs are still lost to various channels. Among them, excitation of surface plasmon polaritons (SPPs) is a critical source of exciton loss, the recovery of which often involves structuring in nanoscale. Herein, a nano‐pattern‐free approach is reviewed to reducing SPP loss that makes use of materials with low refractive index. Because of the limited availability of such low refractive index materials, a method to use a low extraordinary refractive index of birefringent organic semiconductors is explored. With the proposed method combined with common lens‐based outcoupling schemes and high refractive index substrates, it is shown that an ultrahigh external quantum efficiency of ≈72% in a green, single‐junction phosphorescent OLED is within the reach. Transient photoluminescence measurement is used to monitor the change in Purcell factor incurred by the use of the birefringent low refractive index layer and to further verify the validity of the proposed concept.