Surinder Saggar

Abstract Organo‐mineral complexes in various size fractions from the surface horizons of two Chernozemic soils (Typic Argiboroll and Udic Haploboroll) were separated without chemical pretreatment by ultrasonic dispersion in water, followed by sieving and centrifugation. The organic carbon (C), nitrogen (N), and sulfur (S) composition in the size fractions and the degree of polycondensation of humic materials extracted by an alkaline pyrophosphate technique were compared. Fifty‐five to 58% of the organic C was in the clay fraction, with greatest absolute amounts in the coarse clay (2–0.2 µm). Carbon/nitrogen ratios narrowed as particle size decreased. The organic matter separated from the coarse‐clay and fine‐silt fractions (5–2 µm) was dominated by conventional humic acids (HA‐A), which based on their strong adsorption at 280 nm and resistance to acid hydrolysis, were considered strongly aromatic and recalcitrant in soil. In contrast, the organic matter associated with the fine clay (<0.2 µm) was largely fulvic acids (FA‐A, FA‐B) and humic acids (HA‐B) that were less aromatic than conventional humic acids and contained considerable amounts of hydrolyzable N. The fine‐ and coarse‐clay fractions (<2 µm) contained >70% of the total soil S, >80% of the HI‐reducible S, and >64% of the carbohydrate C. In relation to C and N, S was preferentially associated with the fine‐clay fractions. The C/S and N/S ratios decreased substantially from maximum values in the fine‐silt fraction (approximately 120:1 and 10:1, respectively) to minimum values in fine clay (approximately 33:1 and 4.5:1, respectively). The distinct differences between the humus of the coarse clay‐fine silt and the fine‐clay fractions indicate that size fractionation following ultrasonic dispersion in water is a promising method of isolating stable and labile forms of soil organic matter. The data also support earlier hypotheses on the nature of soil S that were based on studies of chemical separation of organic matter from complete soils.

Abstract The agricultural sector in New Zealand is the major contributor to ammonia (NH 3 ), nitrous oxide (N 2 O), and methane (CH 4 ) emissions to the atmosphere. These gases cause environmental degradation through their effects on soil acidification, eutrophication, and stratospheric ozone depletion. With its strong agricultural base and relatively low level of heavy industrial activity, New Zealand is unique in having a greenhouse‐gas‐emissions inventory dominated by the agricultural trace gases, CH 4 and N 2 O, instead of carbon dioxide which dominates in most other countries. About 96% of this anthropogenic CH 4 is emitted by ruminant animals as a byproduct during the process of enteric fermentation. Methane is also produced by anaerobic fermentation of animal manure and many other organic substrates. In pastoral soils, NH 3 and N 2 O gases are generated from N originating from dung, urine, biologically fixed N 2 , and fertiliser. The amount of these gaseous emissions depends on complex interactions between soil properties, climatic factors, and agricultural practices. In this review paper, the animal‐excretal inputs and farm‐effluent applications to New Zealand pastures are quantified. Data from overseas and New Zealand studies on CH 4 , NH 3 , and N 2 O emissions from excretal deposition and animal effluents, and the factors affecting these emissions, are synthesised with an aim to improve the New Zealand estimates of emissions from these sources. The practical implications of these emissions are described in relation to environmental impacts and management strategies for reducing these emissions.