Norman L. Guinasso

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquilibrium solubilities of methane, carbon monoxide, and hydrogen in water and sea waterDenis A. Wiesenburg and Norman L Guinasso Jr.Cite this: J. Chem. Eng. Data 1979, 24, 4, 356–360Publication Date (Print):October 1, 1979Publication History Published online1 May 2002Published inissue 1 October 1979https://pubs.acs.org/doi/10.1021/je60083a006https://doi.org/10.1021/je60083a006research-articleACS PublicationsRequest reuse permissionsArticle Views5183Altmetric-Citations723LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

Biological mixing in deep-sea sediments is described in terms of a time-dependent eddy diffusion model where mixing takes place to a depth L at constant eddy diffusivity D. The differential equation that describes this model has been solved for an impulse source of tracer delivered to the plane surface that forms the top of the mixed layer. The solution then serves as a Green's function, which can be used to determine the distribution of tracer in depth and in time for a surface input of tracer specified as any arbitrary function of time. The characteristic properties of the solution are dependent on the dimensionless parameter D/Lυ, where υ is the sedimentation rate. If D/Lυ is greater than 10, the surface layer becomes homogeneous, and the model is identical to the homogeneous layer model proposed by Berger and Heath (1968). If D/Lυ is less than 0.1, little mixing can take place before the sediments are buried, and so the surface concentration propagates downward into the sediments with little dispersion. For all values of D/Lυ the weighted mean depth of the concentration distribution is the depth at which an impulse source would be found in the sediment if no mixing had taken place. The microtektite data of Glass (1969, 1972) and Glass et al. (1973) indicate that abyssal sediments are mixed from the surface to a maximum mixing depth that ranges between 17 and 40 cm below the surface. Mixing occurs at rates between 1 and 100 cm2 kyr−1. Higher mixing rates may occur nearer the surface, but microtektite distributions cannot be used to estimate these rates in the presence of the deeper, slower mixing. Estimates for D based on dimensional analysis of sediment reworking rates for nearshore organisms (103–106 cm2 kyr−1) are used to predict abyssal mixing rates between 1 and 103 cm2 kyr−1 by invoking the assumption that mixing is proportional to biomass. Plutonium distributions in deep-sea sediments (Noshkin and Bowen, 1973) indicate abyssal mixing rates ranging from 100 to 400 cm2 kyr−1.

We report observations that concern formation and dissociation of gas hydrate near the sea floor at depths of ∼540 m in the northern Gulf of Mexico. In August 1992, three lobes of gas hydrate were partly exposed beneath a thin layer of sediment. By May 1993, the most prominent lobe had evidently broken free and floated away, leaving a patch of disturbed sediment and exposed hydrate. The underside of the gas hydrate was about 0.2 °C warmer than ambient sea water and had trapped a large volume of oil and free gas. An in situ monitoring device, deployed on a nearby bed of mussels, recorded sustained releases of gas during a 44 day monitoring period. Gas venting coincided with a temporary rise in water temperature of 1 °C, which is consistent with thermally induced dissociation of hydrate composed mainly of methane and water. We conclude that the effects of accumulating buoyant force and fluctuating water temperature cause shallow gas hydrate alternately to check and release gas venting.

Here, we report the initial observations of distributions of polycyclic aromatic hydrocarbons (PAH) in subsurface waters near the Deepwater Horizon oil well site (also referred to as the Macondo, Mississippi Canyon Block 252 or MC252 well). Profiles of in situ fluorescence and beam attenuation conducted during 9‐16 May 2010 were characterized by distinct peaks at depths greater than 1000 m, with highest intensities close to the wellhead and decreasing intensities with increasing distance from the wellhead. Gas chromatography/mass spectrometry (GC/MS) analyses of water samples coinciding with the deep fluorescence and beam attenuation anomalies confirmed the presence of polycyclic aromatic hydrocarbons (PAH) at concentrations reaching 189 μ g L −1 (ppb). Subsurface exposure to PAH at levels considered to be toxic to marine organisms would have occurred in discrete depth layers between 1000 and 1400 m in the region southwest of the wellhead site and extending at least as far as 13 km.

Abstract Results from surface geochemical prospecting, seismic exploration and satellite remote sensing have documented oil and gas seeps in marine basins around the world. Seeps are a dynamic component of the carbon cycle and can be important indicators for economically significant hydrocarbon deposits. The northern Gulf of Mexico contains hundreds of active seeps that can be studied experimentally with the use of submarines and Remotely Operated Vehicles (ROV). Hydrocarbon flux through surface sediments profoundly alters benthic ecology and seafloor geology at seeps. In water depths of 500–2000 m, rapid gas flux results in shallow, metastable deposits of gas hydrate, which reduce sediment porosity and affect seepage rates. This paper details the processes that occur during the final, brief transition — as oil and gas escape from the seafloor, rise through the water and dissolve, are consumed by microbial processes, or disperse into the atmosphere. The geology of the upper sediment column determines whether discharge is rapid and episodic, as occurs in mud volcanoes, or more gradual and steady, as occurs where the seep orifice is plugged with gas hydrate. In both cases, seep oil and gas appear to rise through the water in close proximity instead of separating. Chemical alteration of the oil is relatively minor during transit through the water column, but once at the sea surface its more volatile components rapidly evaporate. Gas bubbles rapidly dissolve as they rise, although observations suggest that oil coatings on the bubbles inhibit dissolution. At the sea surface, the floating oil forms slicks, detectable by remote sensing, whose origins are laterally within ∼1000 m of the seafloor vent. This contradicts the much larger distance predicted if oil drops rise through a 500 m water column at an expected rate of ∼0.01 m s −1 while subjected to lateral currents of ∼0.2 m s −1 or greater. It indicates that oil rises with the gas bubbles at speeds of ∼0.15 m s −1 all the way to the surface.