Visible‐Light‐Induced Oxidation/[3+2] Cycloaddition/Oxidative Aromatization Sequence: A Photocatalytic Strategy To Construct Pyrrolo[2,1‐<i>a</i>]isoquinolines

Abstract

Sonnige Aussichten: Durch die im Titel beschriebene Sequenz werden 2-(3,4-Dihydroisochinolin-2(1H)-yl)essigsäureethylester mit einer Reihe elektronenarmer Alkene und Alkine effizient in Pyrrolo[2,1-a]isochinoline umgewandelt (siehe Schema; bpy=2,2′-Bipyridin, EWG = elektronenziehende Gruppe). Die Reaktion bietet eine neue Strategie zum direkten Aufbau der Kernstruktur natürlicher Lamellarin-Alkaloide. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.