Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

Yuan He(Dalian Institute of Chemical Physics), Zilong Huang(Dalian Institute of Chemical Physics), Kaikai Wu(Dalian Institute of Chemical Physics), Juan Ma(Dalian Institute of Chemical Physics), Yong‐Gui Zhou(Dalian Institute of Chemical Physics), Zhengkun Yu(Dalian Institute of Chemical Physics)
Chemical Society Reviews
January 1, 2022
Cited by 331

Abstract

)-H, and alkynyl C(sp)-H, as well as asymmetric carbene insertion to C-H bonds, and more coverage will be given to the recent work. Due to the rapid development of the C-H functionalization area, future directions in this topic are also discussed. This review will give the authors an overview of carbene insertion chemistry in C-H functionalization with focus on the catalytic systems and synthetic applications in C-C bond formation.


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