The Current Status of MOF and COF Applications

Ralph Freund(University of Augsburg), Orysia Zaremba(Basque Center for Materials, Applications and Nanostructures), Giel Arnauts(Catalent (Belgium)), Rob Ameloot(Catalent (Belgium)), Grigorii Skorupskii(Massachusetts Institute of Technology), Mircea Dincă(Massachusetts Institute of Technology), Anastasiya Bavykina(King Abdullah University of Science and Technology), Jorge Gascón(King Abdullah University of Science and Technology), Aleksander Ejsmont(Adam Mickiewicz University in Poznań), Joanna Gościańska(Adam Mickiewicz University in Poznań), Markus J. Kalmutzki(Anton Proksch Institut), Ulrich Lächelt(Center for NanoScience), Evelyn Ploetz(Center for NanoScience), Christian S. Diercks(Lawrence Berkeley National Laboratory), Stefan Wuttke(Ikerbasque)
Angewandte Chemie International Edition
May 14, 2021
Cited by 1,130Open Access
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Abstract

The amalgamation of different disciplines is at the heart of reticular chemistry and has broadened the boundaries of chemistry by opening up an infinite space of chemical composition, structure, and material properties. Reticular design has enabled the precise prediction of crystalline framework structures, tunability of chemical composition, incorporation of various functionalities onto the framework backbone, and as a consequence, fine-tuning of metal-organic framework (MOF) and covalent organic framework (COF) properties beyond that of any other material class. Leveraging the unique properties of reticular materials has resulted in significant advances from both a fundamental and an applied perspective. Here, we wish to review the milestones in MOF and COF research and give a critical view on progress in their real-world applications. Finally, we briefly discuss the major challenges in the field that need to be addressed to pave the way for industrial applications.


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