Electrochemical oxidative thiocyanation and amination of enaminones towards the synthesis of multi-substituted alkenes
Fangling Lu(China XD Group (China)), Kan Zhang(China XD Group (China)), Yanxiu Yao(China XD Group (China)), Ying Yin(Chemical Synthesis Lab), Jiafu Chen(Chemical Synthesis Lab), Xinwei Zhang(Chemical Synthesis Lab), Yin Wang(Chemical Synthesis Lab), Lijun Lu(Wuhan University), Ziwei Gao(China XD Group (China)), Aiwen Lei(Wuhan University)
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Abstract
A highly stereoselective synthesis of thiocyanated enaminones was achieved by an electrochemical process, which involved C–H bond thiocyanation and vinyl C–N bond transamination.
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