Late-stage C(sp<sup>2</sup>)–H and C(sp<sup>3</sup>)–H glycosylation of <i>C</i>-aryl/alkyl glycopeptides: mechanistic insights and fluorescence labeling
Jun Wu(Nephrologisches Zentrum Goettingen), Nikolaos Kaplaneris(Nephrologisches Zentrum Goettingen), Shao‐Fei Ni(Nephrologisches Zentrum Goettingen), Felix Kaltenhäuser(Nephrologisches Zentrum Goettingen), Lutz Ackermann(Nephrologisches Zentrum Goettingen)
Cited by 103Open Access
Abstract
-aryl glycosides, while enabling the assembly of fluorescent-labeled glycoamino acids. The C-H activation approach represents an expedient and efficient strategy for peptide late-stage diversification in a programmable as well as chemo-, regio-, and diastereo-selective fashion.
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