Green synthesis and characterization of tin dioxide nanoparticles for photocatalytic and antimicrobial studies

Sirajul Haq(University of Azad Jammu and Kashmir), Wajid Rehman(Hazara University), Muhammad Waseem(COMSATS University Islamabad), Amreen Shah(Hazara University), Abdul Rehman Khan(University of Azad Jammu and Kashmir), Mahfooz Ur Rehman(Hazara University), Pervaiz Ahmad(University of Azad Jammu and Kashmir), Basharat Khan(Hazara University), Ghazanfar Ali(University of Azad Jammu and Kashmir)
Materials Research Express
January 24, 2020
Cited by 76Open Access
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Abstract

Abstract The tin dioxide nanoparticles (SnO 2 NPs) were fabricated via eco-friendly process using Daphne mucronata ( D. mucronata ) leaves extract as capping and reducing agent. The N 2 adsorption/desorption experiment was performed to determine the surface area by Brunauer–Emmett–Teller (BET) method and S BET was found to be 147 m 2 g −1 . The crystalline nature and lattice parameter was studied by x-ray diffraction (XRD) and calculated crystallite size is 15.63 nm. The surface morphology was examined by scanning electron microscopy (SEM) and the estimated average particle size is 64 nm. The percentage composition and purity of the SnO 2 NPs was determined by energy dispersive x-ray (EDX). The raman active modes were identified by using raman spectroscopy while functional groups upon the surface were studied by using fourier transform infrared (FTIR) spectroscopy. The photocatalytic performance of SnO 2 NPs was examined against Rhodamine 6G (R6G) and 99.70% rhodamine 6G (R6G) were degraded in 390 min with the degradation rate of 0.0148 per min. The SnO 2 NPs were screened against the selected microorganisms and the order of antimicrobial activity is given as; Gram negative bacteria (GNB) > Gram positive bacteria (GPB) > fungi.


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