Large Ln<sub>42</sub> coordination nanorings: NIR luminescence sensing of metal ions and nitro explosives
Dongliang Shi(Wenzhou University), Xiaoping Yang(Wenzhou University), Hongfen Chen(Wenzhou University), Dongmei Jiang(Wenzhou University), Jieni Liu(Wenzhou University), Yanan Ma(Wenzhou University), Desmond Schipper(The University of Texas at Austin), Richard A. Jones(The University of Texas at Austin)
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Abstract
Two 42-metal lanthanide coordination nanorings [Ln42L14(OH)28(OAc)84] (Ln = Nd (1), La (2)) were prepared using a vanillin type ligand. The Nd42 cluster exhibits interesting NIR luminescence sensing behavior to metal ions and nitro explosives.
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