ChemInform Abstract: Stereoselective Synthesis of Conjugated 2,4‐Alkadienoates via the Palladium‐Catalyzed Cross‐Coupling of 1‐Alkenylboronates with 3‐Bromo‐2‐alkenoates.
Teiji Yanagi(Hokkaido University), Takashi Ohe(Hokkaido University), Norio Miyaura(Hokkaido University), Akira Suzuki(Hokkaido University)
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Abstract
Abstract (2E,4E)‐, (2Z,4E)‐ and (2E,4Z)‐2,4‐Alkadienoates can be synthesized in high yields by cross‐coupling of alkenes with alkenyl boron compounds in the presence of a Pd‐catalyst, Na 2 CO 3 or K 2 CO 3 and MeOH or EtOH.
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