Large valley splitting in monolayer <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi mathvariant="bold">WS</mml:mi><mml:mn mathvariant="bold">2</mml:mn></mml:msub></mml:math> by proximity coupling to an insulating antiferromagnetic substrate
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