Catalytic Intermolecular Dicarbofunctionalization of Styrenes with CO<sub>2</sub> and Radical Precursors
Veera Reddy Yatham(Institut Català d'Investigació Química), Yangyang Shen(Institut Català d'Investigació Química), Rubén Martı́n(Institució Catalana de Recerca i Estudis Avançats)
Cited by 296
Abstract
Abstract A redox‐neutral intermolecular dicarbofunctionalization of styrenes with CO 2 at atmospheric pressure and carbon‐centered radicals is described. This mild protocol results in multiple C−C bond‐forming reactions from simple precursors in the absence of stoichiometric reductants, thus exploiting a previously unrecognized opportunity that complements existing catalytic carboxylation events.
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