Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis
James M. Stubbs(Western University), Kelly F. Firth(Western University), Benjamin J. Bridge(Western University), Kathleen J. Berger(Western University), Richard J. Hazlehurst(Western University), P. D. Boyle(Western University), Johanna M. Blacquiere(Western University)
Cited by 11Open Access
Abstract
A highly tunable phosphine-imine ligand family is introduced. Following metallation with ruthenium, deprotonation of the ligand affords a phosphine-enamido species. Complexes with the ligand in both the imine and enamido forms are active toward acceptorless dehydrogenation reactions.
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