Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile

D. Matthew Peacock(University of California, Berkeley), Casey B. Roos(University of California, Berkeley), John F. Hartwig(University of California, Berkeley)
ACS Central Science
September 1, 2016
10.1021/acscentsci.6b00187
Cited by 123Open Access
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Abstract

-BuP. Mechanistic studies indicate that this amination of alkyl halides occurs by a reversible reaction to form a free alkyl radical.

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