Finely tuning MOFs towards high performance in C<sub>2</sub>H<sub>2</sub> storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group
Mingxing Zhang(Collaborative Innovation Center of Advanced Microstructures), Bin Li(Circle (United States)), Yunzhi Li(Nanjing University), Qian Wang(Collaborative Innovation Center of Advanced Microstructures), Wenwei Zhang(Collaborative Innovation Center of Advanced Microstructures), Banglin Chen(Circle (United States)), Shuhua Li(Nanjing University), Yi Pan(Collaborative Innovation Center of Advanced Microstructures), Xiao‐Zeng You(Collaborative Innovation Center of Advanced Microstructures), Junfeng Bai(Collaborative Innovation Center of Advanced Microstructures)
Cited by 149
Abstract
Aiming to improve the acetylene (C2H2) storage capability of MOFs, we successfully designed NJU-Bai 17, a new analogue of MOF-505 with an inserted amide functional group which exhibits almost record high C2H2 uptakes of 222.4 cm(3) g(-1) at 296 K and 296 cm(3) g(-1) at 273 K under 1 bar. This result has been further supported by the determination of the heat of C2H2 adsorption and Grand Canonical Monte Carlo (GCMC) and first-principle calculations.
Related Papers
No related papers found
Powered by citation graph analysis