Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of <i>ortho</i>-Alkenyl Phenols Using an Oxidizing Directing Group
Yangyang Shen(Shanghai Institute of Organic Chemistry), Guixia Liu(Chinese Academy of Sciences), Zhi Zhou(Shanghai Institute of Organic Chemistry), Xiyan Lu(Shanghai Institute of Organic Chemistry)
Cited by 158
Abstract
By using an oxidizing directing group, a mild, efficient Rh(III) catalyzed C–H olefination reaction between N-phenoxyacetamides and alkenes was developed. This reaction provided a straightforward way for the synthesis of ortho-alkenyl phenols, and the directing group is traceless in the product.
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