Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis
Jian Rong(Chinese Academy of Sciences), Ling Deng(Chinese Academy of Sciences), Ping Tan(Chinese Academy of Sciences), Chuanfa Ni(Chinese Academy of Sciences), Yu‐Cheng Gu(Syngenta (United Kingdom)), Jinbo Hu(Chinese Academy of Sciences)
Cited by 386Open Access
Abstract
The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible-light photoredox catalysis. A wide range of readily available mono-, di-, and trifluoromethyl heteroaryl sulfones can thus be used as efficient radical fluoroalkylation reagents under mild conditions. This method not only describes a new synthetic application of fluorinated sulfones, but also provides a new route to fluoroalkyl radicals.
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