Mixed Mg/Li Amides of the Type R<sub>2</sub>NMgCl⋅LiCl as Highly Efficient Bases for the Regioselective Generation of Functionalized Aryl and Heteroaryl Magnesium Compounds

Arkady Krasovskiy(Ludwig-Maximilians-Universität München), Valeria Krasovskaya(Ludwig-Maximilians-Universität München), Paul Knochel(Ludwig-Maximilians-Universität München)
Angewandte Chemie International Edition
March 28, 2006
Cited by 505Open Access
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Abstract

Two are better than one: Mixed lithium-magnesium complexes of the type R2NMgCl⋅LiCl are kinetically highly active bases that convert a range of polyfunctional aromatic and heteroaromatic substrates into the corresponding magnesiated derivatives with high regioselectivity. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z504024_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.


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