Enhanced Electrochromism in Gyroid‐Structured Vanadium Pentoxide

Maik R. J. Scherer(University of Cambridge), Li Li(University of Cambridge), Pedro Cunha(University of Cambridge), Oren A. Scherman(University of Cambridge), Ullrich Steiner(University of Cambridge)
Advanced Materials
January 30, 2012
Cited by 185

Abstract

Manufacturing V2O5 in a 3D periodic highly interconnected gyroid structure on the 10 nm length scale is shown to lead to a significant electrochromic performance enhancement. The structured devices surpass previous inorganic electrochromic materials in all relevant parameters: the switching speed, coloration contrast, and composite coloration efficiency. In particular, the 85 ms switching speed lies within a factor of two of video rate. Enhanced ion intercalation into the gyroid morphology can be extended to other transition-metal oxides and is therefore promising for lithium ion batteries, supercapacitors, and sensors. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.


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