Lithiated Porous Aromatic Frameworks with Exceptional Gas Storage Capacity

Kristina Konstas(CSIRO Manufacturing), James W. Taylor(Materials Science & Engineering), Aaron W. Thornton(CSIRO Manufacturing), Cara M. Doherty(Materials Science & Engineering), Wei Xian Lim(CSIRO Manufacturing), T.J. Bastow(Materials Science & Engineering), Danielle F. Kennedy(Materials Science & Engineering), Colin D. Wood(CSIRO Manufacturing), Barry J. Cox(University of Adelaide), James M. Hill(University of Adelaide), Anita J. Hill(CSIRO Manufacturing), Matthew R. Hill(CSIRO Manufacturing)
Angewandte Chemie International Edition
June 5, 2012
Cited by 133

Abstract

A porous treasure: Porous aromatic framework PAF-1 (see picture, blue structure) has been lithiated, giving a reduced framework with an increased gas storage capacity compared to native PAF-1 (by 22, 71, and 320 % for H2, CH4, and CO2, respectively). The reduced framework was examined spectroscopically, and the potential hydrogen storage capacity was calculated.


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