Synthesis and catalytic properties of MIL-100(Fe), an iron(<scp>iii</scp>) carboxylate with large pores

Patricia Horcajada(Centre National de la Recherche Scientifique), Suzy Surblé(Centre National de la Recherche Scientifique), Christian Serre(Centre National de la Recherche Scientifique), Do‐Young Hong(Korea Research Institute of Chemical Technology), You‐Kyong Seo(Korea Research Institute of Chemical Technology), Jong‐San Chang(Korea Research Institute of Chemical Technology), Jean−Marc Grenèche(Centre National de la Recherche Scientifique), I. Margiolaki(European Science Foundation), Gérard Férey(Université de Versailles Saint-Quentin-en-Yvelines)
Chemical Communications
January 1, 2007
Cited by 1,480

Abstract

The large-pore iron(III) carboxylate MIL-100(Fe) with a zeotype architecture has been isolated under hydrothermal conditions, its structure solved from synchrotron X-ray powder diffraction data, while Friedel-Crafts benzylation catalytic tests indicate a high activity and selectivity for MIL-100(Fe).


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