Solubility of non-polar gases in cyclohexanone between 273.15 and 303.15 K at 101.32 kPa partial pressure of gas

Abstract

Solubility measurements of several non-polar gases (He, Ne, Ar, Kr, Xe, H 2 , D 2 , N 2 , O 2 , C 2 H 4 , C 2 H 6 , CF 4 , SF 6 , andCO 2 ) in cyclohexanone at 273.15 to 303.15 K and a partial pressure of gas of 101.32 kPa, are reported. Gibbs energy, enthalpy, and entropy of solution at 298.15 K and 101.32 kPa partial pressure of gas were evaluated. Effective hard-sphere diameter temperature dependence has been studied and its effect on the calculated SPT (Scaled Particle Theory) solubilities, and enthalpies and entropies of solution was also examined.