Tiny Pd@Co Core–Shell Nanoparticles Confined inside a Metal–Organic Framework for Highly Efficient Catalysis
Yuzhen Chen(University of Science and Technology of China), Qiang Xü(National Institute of Advanced Industrial Science and Technology), Shu‐Hong Yu(University of Science and Technology of China), Hai‐Long Jiang(Hefei National Center for Physical Sciences at Nanoscale)
Cited by 232
Abstract
A new strategy to pre-incorporate metal precursors followed by their in situ reduction is established to prepare tiny core-shell nanoparticles (NPs) stabilized by a metal-organic framework (MOF). The obtained Pd@Co core-shell NPs of ∼2.5 nm confined in the pores of a mesoporous MOF, MIL-101, exhibit synergistic and superior catalytic performance in hydrolytic dehydrogenation of NH3 BH3 under mild conditions compared to their monometallic and alloy counterparts as well as Pd@Co NPs located on a MOF surface.
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