Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using carbon dioxide as a C1 resource

Bo Yu(Chinese Academy of Sciences), Yanfei Zhao(Chinese Academy of Sciences), Hongye Zhang(Chinese Academy of Sciences), Jilei Xu(Chinese Academy of Sciences), Leiduan Hao(Chinese Academy of Sciences), Xiang Gao(Chinese Academy of Sciences), Zhimin Liu(Chinese Academy of Sciences)
Chemical Communications
January 1, 2014
Cited by 110

Abstract

Pd/C-catalyzed direct formylation of aromatic iodides to aryl aldehydes using CO2 as a C1 resource was realized for the first time in the presence of hydrosilanes and base DBU under mild conditions, giving a series of aldehydes in good yields.


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