Amino Acid Based Dynamic Metal–Biomolecule Frameworks
Biplab Joarder(Indian Institute of Science Education and Research Pune), Abhijeet K. Chaudhari(Indian Institute of Science Education and Research Pune), Sanjog S. Nagarkar(Indian Institute of Science Education and Research Pune), Biplab Manna(Indian Institute of Science Education and Research Pune), Sujit K. Ghosh(Indian Institute of Science Education and Research Pune)
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Abstract
On the move: Two isostructural, homochiral Cu(II) coordination frameworks based on amino acids (D- and L-PGA) were synthesized. Dynamic behavior by solid-state structural transformation in single-crystal-to-single-crystal fashion was demonstrated. The extent of structural dynamism was shown by guest inclusion studies. Reversible sol-gel formation and anion-tuning morphology of the compounds is also discussed.
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