The Dimensions of Chain Molecules Containing Branches and Rings

Abstract

Formulas for the mean square radii of various branched and ringed polymer molecules are developed under the usual assumptions regarding the statistics of chain configuration. For branched molecules, the mean square radii vary less rapidly with molecular weight than for strictly linear molecules, while for systems containing only rings and unbranched chains the variation is more rapid than for the linear case. These results show that in principle the quantity of branches or of rings can be determined from light-scattering measurements.