Direct Catalytic Asymmetric Synthesis of Cyclic Aminals fromAldehydes
Xin Cheng(Max Planck Society), S. Vellalath(Max Planck Society), Richard Goddard(Max Planck Society), Benjamin List(Max Planck Society)
Cited by 5Open Access
Abstract
A highly enantioselective Brønsted acid catalyzed direct synthesis of cyclic aminals from aldehydes has been developed. The methodology has been applied to the first asymmetric synthesis of several antihypertensive aminal drugs including (R)-Thiabutazide
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