Metal‐Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light

Matthias Neumann(University of Regensburg), Stefan Füldner(University of Regensburg), Burkhard König(University of Regensburg), Kirsten Zeitler(University of Regensburg)
Angewandte Chemie International Edition
September 28, 2010
Cited by 714

Abstract

The dawn of old stars: Classic xanthene dyes like eosin Y (gr. εoς=goddess of dawn) and green-light irradiation can replace precious metal complexes for the organocatalytic asymmetric α-alkylation of aldehydes, thus rendering the process purely organic.


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