Carborane-based metal–organic frameworks as highly selective sorbents for CO2 over methane
Youn‐Sang Bae(Northwestern University), Omar K. Farha(Northwestern University), Alexander M. Spokoyny(Northwestern University), Chad A. Mirkin(Northwestern University), Joseph T. Hupp(Northwestern University), Randall Q. Snurr(Northwestern University)
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Abstract
Separation of CO(2)/CH(4) mixtures was studied in carborane-based metal-organic framework materials with and without coordinatively unsaturated metal sites; high selectivities for CO(2) over CH(4) ( approximately 17) are obtained, especially in the material with open metal sites.
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