Supermolecular Building Blocks (SBBs) for the Design and Synthesis of Highly Porous Metal-Organic Frameworks
Farid Nouar(University of South Florida), Jarrod F. Eubank(University of South Florida), Till Bousquet(University of South Florida), Łukasz Wojtas(University of South Florida), Michael J. Zaworotko(University of South Florida), Mohamed Eddaoudi(University of South Florida)
Cited by 668
Abstract
Here, we report a novel approach for the bottom-up assembly of hierarchical building blocks: simple molecular building blocks (MBBs) and the resultant supermolecular building blocks (SBBs) to build highly coordinated nets. A specific network, the (3,24)-connected rht, was used as a blueprint to construct a metal-organic framework where the MBBs/SBBs augment the net.
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