Emission Energy Correlates with Inverse of Gold−Gold Distance for Various [Au(SCN)<sub>2</sub>]<sup>-</sup> Salts

N.L. Coker(University of Cincinnati), Jeanette A. Krause Bauer(University of Cincinnati), R. C. Elder(University of Cincinnati)
Journal of the American Chemical Society
December 13, 2003
Cited by 171

Abstract

A series of bis(thiocyanato)gold(I) complexes with Au-Au interactions show luminescence in the range from 500 to 670 nm. The series of salts correlates emission energy with the reciprocal of the Au-Au distance. As the Au-Au distance increases, the emission energy decreases. The ligand system provides no framework for the Au-Au interaction. The emission energy seems totally determined by the Au-Au distance.


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