A monometallic tri-spin single-molecule magnet based on rare earth radicals

N. Zhou(Nankai University), Yue Ma(Nankai University), Chao Wang(Nankai University), Gong Feng Xu(Changchun Institute of Applied Chemistry), Jinkui Tang(Changchun Institute of Applied Chemistry), Jin-Xia Xu(Nankai University), Shi‐Ping Yan(Nankai University), Peng Cheng(Nankai University), Licun Li(Nankai University), Dai‐Zheng Liao(Nankai University)
Dalton Transactions
January 1, 2009
Cited by 104

Abstract

A mononuclear tri-spin single-molecule magnet based on the rare earth radical [Tb(hfac)3(NITPhOEt)2] (NITPhOEt = 4'-ethoxy-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been synthesized, structurally characterized and the alternating current signals show a slow relaxation of magnetization and frequency-dependent signals.


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