The Importance of Hydrogen Bonds for the Structure of Ionic Liquids: Single‐Crystal X‐ray Diffraction and Transmission and Attenuated Total Reflection Spectroscopy in the Terahertz Region
Christian Roth(University of Rostock), Tim Peppel(Leibniz Institute for Catalysis), Koichi Fumino(University of Rostock), Martin Köckerling(University of Rostock), Ralf Ludwig(University of Rostock)
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Abstract
The low-frequency motions in ionic liquids can be studied by transmission and attenuated total reflection spectroscopy in the THz region (see spectrum for 1). These motions involve flexing of individual ions and intermolecular interactions by hydrogen bonding. Combined measurements show that the degree of hydrogen bonding is crucial for the solid structures of this material.
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