Porous Pd-containing polypropylene membranes for catalytic water deoxygenation

V. I. Lebedeva(A.V. Topchiev Institute of Petrochemical Synthesis), V. M. Gryaznov, И. В. Петрова(Russian Academy of Sciences), В. В. Волков(Russian Academy of Sciences), Г. Ф. Терещенко(Russian Academy of Sciences), Е. И. Школьников(Russian Academy of Sciences), L. M. Plyasova(Boreskov Institute of Catalysis), D. I. Kochubey(Boreskov Institute of Catalysis), Rosalie van der Vaart(Institute for Environmental Sciences), E. L. J. van Soest-Verecammen(Institute for Environmental Sciences)
Kinetics and Catalysis
December 1, 2006
Cited by 18

Abstract

Water deoxygenation has been studied in a catalytic membrane reactor in which oxygen is reduced with hydrogen fed into the hollow fiber of a porous polypropylene membrane containing palladium metal on its outer surface. Palladized fibers obtained by different methods and the initial fibers have been characterized by dynamic desorption porosimetry, gas permeability measurements, X-ray structure determination, and light microscopy. The possibility of efficient water deoxygenation at room temperature is demonstrated.


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