Programming a Hydrogen‐Bonding Code for the Specific Generation of a Supermacrocycle
Mark Mascal(University of Nottingham), Nicholas M. Hext(University of Nottingham), Ralf Warmuth(University of Nottingham), M. H. Moore(University of York), J.P. Turkenburg(University of York)
Cited by 108
Abstract
Infinite channels with a diameter 10.5 Å are formed by the DNA-base hybrid 1 in the solid state. These channels arise because 1 specifically communicates the hydrogen bonding codes of the nucleobases cytosine and guanine (“C” and “G”) to unambiguously assemble hexagonal, macrocyclic aggregates 16, which overlap in the crystal.
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