Correlations between magnetic and superconducting properties of Zn-substituted<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">YBa</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Cu</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn><mml:mo>+</mml:mo><mml:mi mathvariant="italic">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>
Abstract
${\mathit{T}}_{\mathit{c}}$ and ${\mathit{T}}_{\mathit{N}}$ (N\'eel) have been measured for a series of ${\mathrm{YBa}}_{2}$(${\mathrm{Cu}}_{0.96}$${\mathrm{Zn}}_{0.04}$${)}_{3}$${\mathrm{O}}_{6+\mathit{x}}$ samples. The T variations of the homogeneous susceptibility ${\mathrm{\ensuremath{\chi}}}_{\mathit{s}}$ of the ${\mathrm{CuO}}_{2}$ planes, given by the shift of the $^{89}\mathrm{Y}$ NMR line, are found to be nearly unchanged with respect to pure samples for x>0.5, which implies that the charge transfer is negligibly modified by Zn, and that the magentic pseudo-gap is not associated with superconducting pairing. Detection of an unusual Curie contribution to the $^{89}\mathrm{Y}$ NMR width for x\ensuremath{\ge}0.5 provides evidence that Zn induces magnetic moments in the ${\mathrm{CuO}}_{2}$ planes, which play a role in the depression of ${\mathit{T}}_{\mathit{c}}$.
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