Economical, Green Synthesis of Fluorescent Carbon Nanoparticles and Their Use as Probes for Sensitive and Selective Detection of Mercury(II) Ions

Wenbo Lu(Chinese Academy of Sciences), Xiaoyun Qin(Chinese Academy of Sciences), Sen Liu(Chinese Academy of Sciences), Guohui Chang(Changchun Institute of Applied Chemistry), Yingwei Zhang(Chinese Academy of Sciences), Yonglan Luo(Changchun Institute of Applied Chemistry), Abdullah M. Asiri(King Abdulaziz University), Abdulrahman O. Al‐Youbi(King Abdulaziz University), Xuping Sun(Chinese Academy of Sciences)
Analytical Chemistry
May 31, 2012
Cited by 1,157

Abstract

The present article reports on a simple, economical, and green preparative strategy toward water-soluble, fluorescent carbon nanoparticles (CPs) with a quantum yield of approximately 6.9% by hydrothermal process using low cost wastes of pomelo peel as a carbon source for the first time. We further explore the use of such CPs as probes for a fluorescent Hg(2+) detection application, which is based on Hg(2+)-induced fluorescence quenching of CPs. This sensing system exhibits excellent sensitivity and selectivity toward Hg(2+), and a detection limit as low as 0.23 nM is achieved. The practical use of this system for Hg(2+) determination in lake water samples is also demonstrated successfully.


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