Transition-Metal-Free: A Highly Efficient Catalytic Aerobic Alcohol Oxidation Process
Renhua Liu(Dalian Institute of Chemical Physics), Xinmiao Liang(Chinese Academy of Sciences), Chunyan Dong(Chinese Academy of Sciences), Xinquan Hu(Dalian Institute of Chemical Physics)
Cited by 423
Abstract
A highly efficient catalytic system without transition metals has been developed for aerobic alcohol oxidations. Under the optimal reaction conditions, various alcohol substrates were converted into their corresponding carbonyl compounds by air with TEMPO/Br2/NaNO2 as catalyst, especially the oxidation of benzylic alcohols to benzaldehydes in high yields.
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