Photocontrolled nucleobase binding to an organometallic RuII arene complex
S. Betanzos-Lara(University of Warwick), Luca Salassa(University of Warwick), Abraha Habtemariam(University of Warwick), Peter J. Sadler(University of Warwick)
Cited by 102
Abstract
The complex [(p-cym)Ru(bpm)(py)][PF6]2 (where p-cym = para-cymene, bpm = 2,2′-bipyrimidine and py = pyridine) is the first ruthenium(II) arene complex that can selectively photodissociate a monodentate ligand (py) when excited with visible light and form a reactive aqua derivative able to bind to a DNA base.
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