Insertion of Arynes into σ Bonds
Diego Peña(Universidade de Santiago de Compostela), Dolores Pérez(Universidade de Santiago de Compostela), Enrique Guitián(Universidade de Santiago de Compostela)
Cited by 224
Abstract
Enjoying a revival: Following a quiet period, numerous reports have recently appeared regarding the insertion of arynes into σ bonds (see scheme) as a result of milder, high-yielding methods for generating arynes and the introduction of palladium catalysis into aryne chemistry. The methodology shows promise as a means of preparing complex ortho-disubstituted arenes.
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