The unique rht-MOF platform, ideal for pinpointing the functionalization and CO<sub>2</sub>adsorption relationship
Ryan Luebke(King Abdullah University of Science and Technology), Jarrod F. Eubank(University of South Florida), Amy Cairns(King Abdullah University of Science and Technology), Youssef Belmabkhout(King Abdullah University of Science and Technology), Łukasz Wojtas(University of South Florida), Mohamed Eddaoudi(University of South Florida)
Cited by 166
Abstract
The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO(2) uptake in the resultant rht-MOF.
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